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The Social Security number is divided as follows: the area number (first three digits), group number (fourth and fifth digits), and serial number (last four digits).
To determine if an SSN is invalid consider the following: No SSNs with an area number in the 800 or 900 series, or "000" area number, have been assigned.
See here for details to see if a Social Security number is valid :
http://www.socialsecurity.gov/employer/ssnvhighgroup.htm